DP Chemistry · HL / SL · Structure 1. Models of the particulate nature of matter · Updated

S1.2 The nuclear atom

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Introduction: The Nuclear Atom

Every element in the universe is defined by something astonishingly small — the nucleus at the centre of its atoms. Understanding atomic structure is the foundation of all chemistry: it explains why elements have unique identities, why isotopes exist, and how atomic mass is calculated.

In this subtopic, we explore:

  • The three subatomic particles and their properties
  • How nuclear symbols encode an atom's structure
  • What isotopes are and how to calculate relative atomic mass
  • How to interpret mass spectra (a key analytical tool)
Analogy

Think of the atom like a vast, mostly empty stadium. The nucleus is a marble sitting at the centre — tiny, but containing almost all the mass. The electrons are like scattered specks of dust somewhere in the stands.

Subatomic Particles: Protons, Neutrons, and Electrons

Atoms are composed of three types of subatomic particles, each with distinct properties:

Nucleus

The nucleus is the dense, positively charged core of an atom containing protons and neutrons, collectively called nucleons.

ParticleRelative MassRelative ChargeLocation
Proton1+1Nucleus
Neutron10Nucleus
ElectronNegligible (~1/1836)−1Outside nucleus

Key points:

  • Protons define the element. An atom with 6 protons is always carbon — no exceptions.
  • Neutrons stabilise the nucleus by offsetting proton-proton repulsion. Their number can vary, giving rise to isotopes.
  • Electrons determine chemical behaviour. Their arrangement around the nucleus controls how atoms bond and react.
  • In a neutral atom, the number of electrons equals the number of protons.
Note

Actual particle masses are on the order of kg — far too small for everyday use. Relative masses expressed in atomic mass units (amu) make calculations manageable. Protons and neutrons each have a relative mass of 1; the electron's mass is so small it is treated as negligible.

Subatomic Particles: Protons, Neutrons, and Electrons

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