MYP 4 Chemistry · Structure 1: It Matters!

Chromatography

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  1. Question 1

    In paper chromatography, which of the following correctly identifies the stationary phase and mobile phase?
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    AStationary phase: absorbent paper; Mobile phase: liquid solvent

    Step-by-step walkthrough

    Choose a solution method

    Method #1Direct Approach

    Step 1: Define the two phases

    In chromatography, the stationary phase is the material that stays still, while the mobile phase is the material that moves through it carrying the substances.

    Step 2: Match to paper chromatography

    In paper chromatography specifically, the absorbent paper does not move — it is the stationary phase. The liquid solvent travels up the paper by capillary action — it is the mobile phase.

    Step 3: Choose the correct answer

    The correct answer is: Stationary phase: absorbent paper; Mobile phase: liquid solvent. The sample mixture is neither a phase — it is what gets separated by the two phases.

    Method #2Process of Elimination

    Step 1: What is being asked?

    The question asks us to correctly pair the stationary and mobile phases specifically in paper chromatography.

    Step 2: Eliminate reversed options

    'Stationary phase: liquid solvent; Mobile phase: absorbent paper' is wrong — the solvent moves, so it cannot be stationary. The paper does not move, so it cannot be the mobile phase.

    Step 3: Eliminate options involving the sample

    'Stationary phase: the sample mixture; Mobile phase: absorbent paper' and 'Stationary phase: liquid solvent; Mobile phase: the sample mixture' are both wrong — the sample mixture is what gets separated, not a phase in the system.

    Step 4: Select the correct answer

    The remaining option — 'Stationary phase: absorbent paper; Mobile phase: liquid solvent' — is correct and matches the definitions.

  2. Question 2

    A student runs a paper chromatography experiment. The solvent front travels 9.0 cm from the baseline. A red spot travels 6.3 cm from the baseline. What is the Rf value of the red substance?
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    A0.70

    Step-by-step walkthrough

    Choose a solution method

    Method #1Direct Approach

    Step 1: Recall the Rf formula

    The Rf value is calculated using:

    Step 2: Substitute the values

    Distance travelled by the red spot = 6.3 cm, distance travelled by solvent front = 9.0 cm.

    Step 3: Calculate the result

    The Rf value is 0.70 (no units, since it is a ratio).

    Method #2Process of Elimination

    Step 1: What is being asked?

    We need to calculate the Rf value, which must be between 0 and 1 since a substance can never travel further than the solvent front.

    Step 2: Eliminate values greater than 1

    1.43 is greater than 1, which is impossible for an Rf value. This would suggest the substance travelled further than the solvent, which cannot happen.

    Step 3: Check the calculation for remaining options

    0.63 would come from (wrong denominator). 0.57 would come from (also wrong). Only 0.70 comes from , which uses the correct values.

    Step 4: Select the correct answer

    The correct Rf value is 0.70, calculated correctly as .

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