MYP 4 Chemistry · Structure 2: Bonding and Beyond

Covalent Bonds - Structure and Properties

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  1. Question 1

    A hydrogen atom has 1 outer electron, and a chlorine atom has 7 outer electrons. When these two atoms form a covalent bond, how many electrons does each atom count in its outer shell after bonding?
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    Correct answerCorrect!Incorrect
    AHydrogen counts 2, chlorine counts 8

    Step-by-step walkthrough

    Choose a solution method

    Method #1Direct Approach

    Step 1: Identify what a covalent bond does

    In a covalent bond, both atoms share the same pair of electrons. Both atoms count the shared pair as part of their own outer shell.

    Step 2: Count electrons for hydrogen

    Hydrogen contributes 1 electron to the shared pair. Because it shares with chlorine's 1 electron, it now counts 2 electrons in its shell. Hydrogen only needs 2 for a full shell, so it is now stable. ✓

    Step 3: Count electrons for chlorine

    Chlorine already has 7 outer electrons. It contributes 1 to the shared pair, and it also counts the hydrogen's 1 electron. So chlorine counts 7 + 1 = 8 electrons in its outer shell. ✓

    Step 4: Select the correct answer

    Hydrogen counts 2 and chlorine counts 8. Both atoms have achieved a full outer shell through sharing.

    Method #2Process of Elimination

    Step 1: Identify what is being asked

    The question asks how many electrons each atom counts in its shell after the covalent bond forms, remembering that the shared pair belongs to both atoms.

    Step 2: Eliminate 'Hydrogen counts 1, chlorine counts 7'

    This option shows no change from before bonding. Since the whole point of covalent bonding is to share electrons so both atoms reach a full shell, this cannot be correct.

    Step 3: Eliminate 'Hydrogen counts 2, chlorine counts 7'

    Hydrogen correctly counts 2, but chlorine is shown as still having only 7. Chlorine must count the shared pair too, giving it 8 — so this option is wrong.

    Step 4: Eliminate 'Hydrogen counts 1, chlorine counts 8'

    Chlorine correctly reaches 8, but hydrogen is shown as only counting its own original electron (1). After sharing, hydrogen counts 2. This option is wrong.

    Step 5: Select the correct answer

    The only remaining option is 'Hydrogen counts 2, chlorine counts 8' — both atoms count the shared pair, achieving full outer shells.

  2. Question 2

    In a dot-and-cross diagram for a water molecule (H₂O), how many lone pairs are shown on the oxygen atom?
    No clue? Show me the answer
    Correct answerCorrect!Incorrect
    A2

    Step-by-step walkthrough

    Choose a solution method

    Method #1Direct Approach

    Step 1: Identify the outer electrons of oxygen

    Oxygen is in Group 6 of the periodic table, so it has 6 outer electrons.

    Step 2: Determine how many bonds oxygen forms

    Oxygen needs 2 more electrons to complete its shell of 8. It forms 2 single bonds — one with each hydrogen atom. Each bond uses 1 of oxygen's outer electrons.

    Step 3: Calculate the remaining electrons

    Oxygen has 6 outer electrons. It uses 2 in bonding (one per bond). The remaining electrons are non-bonding. These are arranged as 2 lone pairs (each lone pair = 2 electrons).

    Step 4: Select the correct answer

    There are 2 lone pairs on the oxygen atom in a water molecule. These are drawn on the outside of the oxygen atom in the dot-and-cross diagram.

    Method #2Process of Elimination

    Step 1: Identify what is being asked

    We need the number of lone pairs (non-bonding electron pairs) on oxygen in H₂O. Oxygen has 6 outer electrons and forms 2 bonds with hydrogen.

    Step 2: Eliminate '0 lone pairs'

    If oxygen had 0 lone pairs, all 6 outer electrons would be in bonds. But only 2 of oxygen's electrons are used for bonding (one per O–H bond), so 0 lone pairs is incorrect.

    Step 3: Eliminate '1 lone pair'

    1 lone pair = 2 electrons used as lone pair + 2 used in bonds = 4 electrons accounted for. But oxygen has 6 outer electrons, so 1 lone pair leaves 2 electrons unaccounted for. This is incorrect.

    Step 4: Eliminate '3 lone pairs'

    3 lone pairs = 6 non-bonding electrons. But oxygen also needs 2 electrons for its 2 bonds, making a total of 8, which exceeds the 6 outer electrons oxygen actually has. This is impossible.

    Step 5: Select the correct answer

    2 lone pairs accounts for 4 non-bonding electrons + 2 bonding electrons = 6 outer electrons in total. This is the correct answer.

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